ChemInform Abstract: RHODIUM(I) CATALYZED ASYMMETRIC HYDROGENATION OF α‐ACETAMIDOCINNAMIC ACID WITH MONOMERIC AND POLYMERIC AMINOPHOSPHINES

Nagel, Ulrich; Menzel, Hartmut; Lednor, Peter W.; Beck, Wolfgang; Guyot, A.; Bartholin, M.

doi:10.1002/chin.198136130

Cited by 2 publications

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“…The reduction of N-acetyl-a-aminocinnamic acid in the presence of [Rh(C 8 H 14 )Cl] 2 and the ligand 53 gives the product in an optical yield reaching 77%. 94 Ligands 54, 55a,b, 56, 57a,b, 58 and 59a,b 95,96 have been used in the hydrogenation of N-acetyl-a-aminocinnamic and N-benzoyl-aaminocinnamic acids in the presence of [Rh(C 6 H 8 )Cl] 2 . The maximum optical yield (68%) was attained in the case of (S)-1-[2-(methyl-tert-butylphosphino)phenyl]ethylamine (58).…”

Section: Other Groups Of Chiral Pn-bidentate Ligandsmentioning

confidence: 99%

Chiral P,N-bidentate ligands in coordination chemistry and organic catalysis involving rhodium and palladium

Gavrilov¹,

Polosukhin²

2000

Russ. Chem. Rev.

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Published data on the synthesis of rhodium and palla-Published data on the synthesis of rhodium and palladium complexes with optically active P,N-bidentate ligands and dium complexes with optically active P,N-bidentate ligands and their applications in homogeneous asymmetric catalysis are their applications in homogeneous asymmetric catalysis are summarised and discussed. The effect of the nature of the P,N-summarised and discussed. The effect of the nature of the P,Nbidentate compounds on the structure of the metal complexes and bidentate compounds on the structure of the metal complexes and on enantioselectivity in catalysis is examined. Allylic substitution, on enantioselectivity in catalysis is examined. Allylic substitution, cross-coupling, hydroboration and hydrosilylation catalysed by cross-coupling, hydroboration and hydrosilylation catalysed by Rh or Pd complexes with optically active P,N-bidentate ligands Rh or Pd complexes with optically active P,N-bidentate ligands are considered. The prospects for the development of this field of are considered. The prospects for the development of this field of chemistry are demonstrated. The bibliography includes 186 refer-chemistry are demonstrated. The bibliography includes 186 references ences. .

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Section: Other Groups Of Chiral Pn-bidentate Ligandsmentioning

confidence: 99%

Chiral P,N-bidentate ligands in coordination chemistry and organic catalysis involving rhodium and palladium

Gavrilov¹,

Polosukhin²

2000

Russ. Chem. Rev.

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“…Zur Fixierung von Metallcarbonylverbindungen wurden bisher vor allem N-und PLiganden verwendet [2]. In Fortführung unserer Untersuchungen über polymere Metallkomplexe [3,4] berichten wir über die Synthese von Polystyrolderivaten mit Isocyanidfunktionen und die Fixierung von Metallcarbonylen auf diesen Trägern.…”

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Fixierung von Metallcarbonylen auf Poly-Isocyaniden [1] / Anchoring of Metal Carbonyls on Poly Isocyanides [1]

Menzel¹,

Fehlhammer²,

Beck³

1982

Zeitschrift Für Naturforschung B

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Abstract Polyisocyanides with the groups -CH2N ≡ C and -C(O)O(CH2)2N≡C attached to polystyrene have been prepared and reacted with various metal carbonyl compounds resulting in the fixation on the polymeric supports of-M(CO)5, -M(CO)4 (M = Cr, Mo, W), -MO(Cl)(η-C5H5)(CO)2, -Mn2(CO)η -Mn(CO)ηX (N = 3, 4; X = Cl, Br), -Fe(CO)4, -Fe3(CO)11, -FeI2(CO)2, -FeX(η-C5H5)(CO) (X = Cl, Br, I), -Ru(CO)4, -Ru3(CO)9, ,,-Os3H2(CO)10", and -RhCl(CO)2. The cyano complexes [Fe(CN)2(η-C5H5)CO]- and [Mo(CN)2(η-C5H5)(CO)2]- have been immobilized by alkylation with chloromethylated polystyrene

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ChemInform Abstract: RHODIUM(I) CATALYZED ASYMMETRIC HYDROGENATION OF α‐ACETAMIDOCINNAMIC ACID WITH MONOMERIC AND POLYMERIC AMINOPHOSPHINES

Cited by 2 publications

References 1 publication

Chiral P,N-bidentate ligands in coordination chemistry and organic catalysis involving rhodium and palladium

Chiral P,N-bidentate ligands in coordination chemistry and organic catalysis involving rhodium and palladium

Fixierung von Metallcarbonylen auf Poly-Isocyaniden [1] / Anchoring of Metal Carbonyls on Poly Isocyanides [1]

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