ChemInform Abstract: Rhodium(II) Acetate Catalyzed Hydrosilylation of Enamides and N‐ Vinylureas Leading to 1‐(Trialkylsilyl)alkylamine Derivatives.

Abstract

Rhodium(II) Acetate Catalyzed Hydrosilylation of Enamides and N-Vinylureas Leading to 1-(Trialkylsilyl)alkylamine Derivatives. -The title reaction proceeds smoothly in a regio-and site-selective manner. The use of HSiCl3 or HSi(O-Et)3 as hydrosilylation agents failed. -(MURAI, T.; ODA, T.; KIMURA, F.; ONISHI, H.; KANDA, T.; KATO, S.; J.