ChemInform Abstract: Ruthenium‐Catalyzed Synthesis of Highly Substituted Pyrroles from 1‐Vinylpropargyl Alcohols and Amines.

Abstract

Ruthenium-Catalyzed Synthesis of Highly Substituted Pyrroles from 1-Vinylpropargyl Alcohols and Amines. -Depending on the substituents on the amine, the initial pyrrole cyclization can be followed by [3,3] rearrangements or Diels-Alder reactions to yield products (X), (XI), (XII), (XIII), or (XV). -(THIES, N.; GERLACH, M.; HAAK*, E.; Eur. J. Org. Chem. 2013, 32, 7354-7365, http://dx.doi.org/10.1002/ejoc.201300803 ; Chem. Inst., Otto-von-Guericke-Univ., D-39106 Magdeburg, Germany; Eng.) -Roessler