Chemischer Informationsdienst
 1981
DOI: 10.1002/chin.198104161
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ChemInform Abstract: SILICON‐DIRECTED BAEYER‐VILLIGER REACTIONS. STEREOSPECIFIC SYNTHESIS OF OLEFINIC ACIDS AND ESTERS

Paul F. Hudrlik1,
Anne M. Hudrlik2,
G. Nagendrappa3
et al.

Abstract: Baeyer‐Villiger‐Reaktion der Silylketone (I) bzw. (V) in Gegenwart von NazHPO4 ‐Puffer liefert die Lactone (II) bzw. (VI) [das instabile Lacton (VIb) ist mit dem stabilen Isomeren (IX) verunreinigt], die zu den Hydroxysilanen (III) bzw. (VII) verseift werden.

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