ChemInform Abstract: Solvothermal Syntheses of Three New One‐Dimensional Ternary Selenidostannates: [DBNH][M_1/2Sn_1/2Se₂] (M: Mn, Zn, Hg).

Abstract

Solvothermal Syntheses of Three New One-Dimensional Ternary Selenidostannates: [DBNH][M1/2Sn1/2Se2] (M: Mn, Zn, Hg). -Compounds (IV) and (VI) crystallize in the tetragonal space group P42/ncm with Z = 4 (single crystal XRD). The structures contain straight one-dimensional [M0.5Sn0.5Se2 (M: Mn, Zn, Hg) chains formed by edge-sharing M0.5Sn0.5Se4 tetrahedra. The new compounds are further characterized by solid state UV/VIS diffuse reflectance spectroscopy. -(XIONG, W.-W.; LI, P.-Z.; ZHOU, T.-H.; ZHAO, Y.; XU, R.; ZHANG*, Q.; J. Solid State Chem. 204 (2013) 86-90, http://dx.