ChemInform Abstract: Stereochemistry of Metal‐Ammonia Ring Reduction of Aryl Carboxylates and Ketones and NMR Conformational Analysis of the Dihydro Aromatic Products.
Abstract:Während die Reduktion der Anthracene (I) mit Natrium in flüssigem Ammoniak fast ausschließlich zu den cis‐Dihydro‐Derivaten (II) führt, entstehen aus den Naphthalinen (III) Gemische aus den trans‐ und cis‐Verbindungen (IV) und (V).
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