Chemischer Informationsdienst
 1974
DOI: 10.1002/chin.197420225
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ChemInform Abstract: STEREOCHEMISTRY OF THE ELECTROPHILIC ADDITION OF BROMINE TO DIBENZO(B,F)THIEPIN AND ITS 5,5‐DIOXIDE

Mihäly Nógrádi1,
W. D. Ollis2,
I. O. Sutherland3

Abstract: Während die Bromierung des Dibenzothiepins (I) mit Brom in CH2Cl2 ein Gemisch der isomeren Dibromide (IIa) und (IIb) gibt, liefert die Bromierung in Essigsäure bei 20°C ausschließlich (IIb) (73% Ausbeute).

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