ChemInform Abstract: Stereodefined Construction of Trisubstituted Alkenes by Direct Coupling Reaction of Allylating Agents, Alkynes, and Organoboranes.

Fukushima, Masahiro; Takushima, Daiki; Satomura, Hideaki; Onodera, Gen; Kimura, Masanari

doi:10.1002/chin.201245056

ChemInform

2012

DOI: 10.1002/chin.201245056

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ChemInform Abstract: Stereodefined Construction of Trisubstituted Alkenes by Direct Coupling Reaction of Allylating Agents, Alkynes, and Organoboranes.

Masahiro Fukushima

Daiki Takushima

Hideaki Satomura

et al.

Abstract: The palladium‐catalyzed three‐component coupling reaction of allylic alcohols, terminal alkynes, and organoboranes preferentially gives (E)‐substituted alkylpentadienes, involving geminal allylation and alkylation at the acetylenic terminal carbon.

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ChemInform Abstract: Stereodefined Construction of Trisubstituted Alkenes by Direct Coupling Reaction of Allylating Agents, Alkynes, and Organoboranes.

Abstract: The palladium‐catalyzed three‐component coupling reaction of allylic alcohols, terminal alkynes, and organoboranes preferentially gives (E)‐substituted alkylpentadienes, involving geminal allylation and alkylation at the acetylenic terminal carbon.

Cited by 0 publications

References 1 publication

No citations

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