1988
DOI: 10.1002/chin.198821128
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ChemInform Abstract: Stereospecific Synthesis of Conjugate Dienecarboxylic Acid Esters and Dienones.

Abstract: ChemInform Abstract Palladium-catalyzed cross condensation of the alkenylboronic acid (I) with the unsaturated bromo compounds (II) yields the dienes (III) with retention of the configuration at both double bonds of the educts.

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“…250 ± 254 Thus this reaction has been used to prepare hydroprene (239) from alkenylboronic acid 240. 255,256 An interesting methodological expedient is to carry out this process in the aqueous acetonitrile medium. 257 The reaction was catalysed by a system comprising Pd(OAc) 2 and water-soluble sulfonated triphenylphosphine, P(C 6 H 4 SO 3 H) 3 .…”
Section: The Suzuki Reaction and Its Modificationsmentioning
confidence: 99%
“…250 ± 254 Thus this reaction has been used to prepare hydroprene (239) from alkenylboronic acid 240. 255,256 An interesting methodological expedient is to carry out this process in the aqueous acetonitrile medium. 257 The reaction was catalysed by a system comprising Pd(OAc) 2 and water-soluble sulfonated triphenylphosphine, P(C 6 H 4 SO 3 H) 3 .…”
Section: The Suzuki Reaction and Its Modificationsmentioning
confidence: 99%