ChemInform Abstract: Structural Studies of Organoboron Compounds. Part 57. Synthesis and Structure of Bicyclic Boron‐Nitrogen Betaines. 1‐Methyl‐5‐(3‐ nitrophenyl)‐4,6,9‐trioxa‐1‐azonia‐5‐boratabicyclo(3.3.1)nonane and 3, 3,4‐Trimethyl‐1‐(3‐nitrophenyl)‐2,6,7‐trioxa‐3‐azonia‐1‐boratabicyclo( 2.2.2)octane.

Ahlenstiel, Eckart; Kliegel, Wolfgang; Rettig, Steven J.; Trotter, James

doi:10.1002/chin.199330211

ChemInform

1993

DOI: 10.1002/chin.199330211

|View full text |Cite

ChemInform Abstract: Structural Studies of Organoboron Compounds. Part 57. Synthesis and Structure of Bicyclic Boron‐Nitrogen Betaines. 1‐Methyl‐5‐(3‐ nitrophenyl)‐4,6,9‐trioxa‐1‐azonia‐5‐boratabicyclo(3.3.1)nonane and 3, 3,4‐Trimethyl‐1‐(3‐nitrophenyl)‐2,6,7‐trioxa‐3‐azonia‐1‐boratabicyclo( 2.2.2)octane.

Eckart Ahlenstiel

Wolfgang Kliegel

Steven J. Rettig

et al.

Abstract: ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...

Citation Types

Supporting

Mentioning

Contrasting

Year Published

1993

Publication Types

Select...

Article1

Relationship

Self Cite0

Independent1

Authors

Journals

Cited by 1 publication

References 1 publication

Supporting

Mentioning

Contrasting

Order By: Relevance

Structural studies of organoboron compounds. LVII. Synthesis and structure of bicyclic boron-nitrogen betaines. 1-Methyl-5-(3-nitrophenyl)-4,6,9-trioxa-1-azonia-5-boratabicyclo[3.3.1]nonane and 3,3,4-trimethyl-1-(3-nitrophenyl)-2,6,7-trioxa-3-azonia-1-boratabicyclo[2.2.2]octane

Ahlenstiel¹,

Kliegel²,

Rettig³

et al. 1993

Can. J. Chem.

View full text Add to dashboard Cite

The syntheses and structures of the bicyclic boron-nitrogen betaines l-methyl-5-(3-nitrophenyl)- 4,6, 7a, and 3,3, Introductionoxide 5 undergoing an intramolecular 0 + B coordination The condensation of bis(2-hydroxyethy1)amines 1 and arylboronic acids leads to 1,3-dioxa-6-aza-2-boracyclooctanes 2 that are known to undergo transannular N + B coordination to form the stable bicyclo[3.3.0]octane ring systems 3. The structure 3 for these materials has been confirmed by chemical and physical investigations ( I ) , including an X-ray crystallographic analysis of the N-unsubstituted derivative 3 (R = H, Ar = C6H,) (2). Employing the Noxides 4, obtained by reaction of 1 with hydrogen peroxide (3,4), the condensation with an arylboronic acid could result in both the eight-membered cyclic arylboronate 5 and the six-membered chelate 6.4 Both products (5 and 6) could subsequently cyclize to the bridged-ring compound 7 , the N-

show abstract

Structural studies of organoboron compounds. LVII. Synthesis and structure of bicyclic boron-nitrogen betaines. 1-Methyl-5-(3-nitrophenyl)-4,6,9-trioxa-1-azonia-5-boratabicyclo[3.3.1]nonane and 3,3,4-trimethyl-1-(3-nitrophenyl)-2,6,7-trioxa-3-azonia-1-boratabicyclo[2.2.2]octane

Ahlenstiel¹,

Kliegel²,

Rettig³

et al. 1993

Can. J. Chem.

View full text Add to dashboard Cite

show abstract

scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.

Contact Info

customersupport@researchsolutions.com

10624 S. Eastern Ave., Ste. A-614

Henderson, NV 89052, USA

This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.

Blog Terms and Conditions API Terms Privacy Policy Contact Cookie Preferences Do Not Sell or Share My Personal Information

Made with 💙 for researchers

Part of the Research Solutions Family.

Cited by 1 publication

References 1 publication

Structural studies of organoboron compounds. LVII. Synthesis and structure of bicyclic boron-nitrogen betaines. 1-Methyl-5-(3-nitrophenyl)-4,6,9-trioxa-1-azonia-5-boratabicyclo[3.3.1]nonane and 3,3,4-trimethyl-1-(3-nitrophenyl)-2,6,7-trioxa-3-azonia-1-boratabicyclo[2.2.2]octane

Structural studies of organoboron compounds. LVII. Synthesis and structure of bicyclic boron-nitrogen betaines. 1-Methyl-5-(3-nitrophenyl)-4,6,9-trioxa-1-azonia-5-boratabicyclo[3.3.1]nonane and 3,3,4-trimethyl-1-(3-nitrophenyl)-2,6,7-trioxa-3-azonia-1-boratabicyclo[2.2.2]octane

Contact Info

Product

Resources

About