ChemInform Abstract: Synthesis of 2‐Aryl‐1,3‐cyclopentanediones Through Catalytic Borylation as a Key Step.

Abstract

Synthesis of 2-Aryl-1,3-cyclopentanediones Through Catalytic Borylation as a KeyStep. -Sequential Suzuki-type coupling between -iodocyclopentenone (I) and arylboronic acids followed by borylation and oxidative workup furnishes the title compounds in a one-pot manner in moderate yields. -(PALAU-LLUCH, G.; FERNANDEZ*, E.; Asian J. Org. Chem. 4 (2015) 9, 963-968, http://dx.doi.org/10.1002/ajoc.201500229 ; Dep. Phys. Inorg. Chem., Univ. Rovira Virgili, E-43007 Tarragona, Spain; Eng.) -M. Tismer 03-063