ChemInform Abstract: Synthesis of a Luminescent Azaphosphole.

Abstract

Synthesis of a Luminescent Azaphosphole. -A carbazole-based azaphosphole (VI) is prepared by acid-catalyzed dehydrocyclization of 1-phosphino-9H-carbazole (IV) with toluyl chloride (V). Compound (VI) displays significant fluorescence in solution. -(WU, S.; RHEINGOLD, A. L.; GOLEN, J. A.; GRIMM, A. B.; PROTASIEWICZ*, J. D.; Eur. J. Inorg. Chem. 2016, 5, 768-773, http://dx.doi.org/10.1002/ejic.201501279 ; Dep. Chem., Case West. Reserve Univ., Cleveland, OH 44106, USA; Eng.) -R. Langenstrassen 27-208