ChemInform Abstract: Synthesis of Ether‐Linked Di‐ and Trisaccharide Derivatives. Part 2. Functionalization and Potential Applications of Ether‐Linked Di‐ and Trisaccharides Containing D‐Glucose.

Abstract

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Neodisaccharide diglycosyl compounds: Ethers, thioethers and selenoethers. A survey of their synthesis and biological activity

“…A neotrisaccharide 9 was obtained by coupling of a neodisaccharide 5,6epoxide 8 with an excess of diacetone D-glucose 5 (2 equiv.) in 61% yield (Scheme 3) [14], while coupling of a Dmannose 5,6-epoxide with a D-xylose OH-3 alcohol (2 equiv.) gave a D-Xyl(3-6)-D-Man neodisaccharide (74%) along with a small amount (8%) of the neotrisaccharide [15].…”