ChemInform Abstract: Synthesis of Haterumalide NA

Abstract

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Tetrahydrofuran-Containing Macrolides: A Fascinating Gift from the Deep Sea

“…From a structural point of view, these molecules display many interesting motifs in their complex frameworks, such as the THF ring bridged with a macrocyclic lactone, a Z chlorovinyl functionality, two allylic alcohols, and several stereogenic centers (Table ). Helpful and complete reviews were published in 2007 and 2009 about the isolation, structures, bioactivities, and total synthesis of haterumalides, biselides, and related natural products. In our review, mention is made only to papers after Kigoshi’s review.…”