ChemInform Abstract: Synthesis of Phosphonate Analogues of 2‐Deoxyribose‐1‐phosphate.

Abstract

Synthesis of Phosphonate Analogues of 2-Deoxyribose-1-phosphate. -Different types of phosphonate analogues (III)/(IV) and (IX) of 2deoxyribose are prepared for the first time by a Lewis acid mediated reaction of glycosyl donors (I) and (VII) with diisopropyl hydroxymethylphosphonate (II) or triisopropyl phosphite (VIII). -(RUBIRA, M.-J.; PEREZ-PEREZ, M.-J.; BALZARINI, J.; CAMARASA, M.-J.; Synlett (1998) 2, 177-179; Inst. Quim. Med., CSIC, E-28006 Madrid, Spain; EN)