ChemInform Abstract: Synthetic Organic Electrochemistry: An Enabling and Innately Sustainable Method

Horn, Evan J.; Rosen, Brandon R.; Baran, Phil S.

doi:10.1002/chin.201631262

Cited by 1 publication

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“…[96] The anodic oxidation of a heteroatomcontaining substrate produces a radical which can then be adhered to alkene C=C double bond to develop a carbon radical, which finds further utilization in different functionalization reactions such as aziridination, azidoiodination, oxysulfurization, and aminooxygenation. [97]…”

Section: Tempo Mediated Electrochemical Oxidations Of Alkenesmentioning

confidence: 99%

2,2,6,6‐Tetramethylpiperidinyloxyl (TEMPO) Radical Mediated Electro‐Oxidation Reactions: A Review

et al. 2021

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Over the last few decades, the interest in green and sustainable chemistry has led to the development of different synthetic methodologies which utilize clean reagents. In that direction, the electro-oxidation reactions are considered as one of the most interesting and promising methods. This is predominantly due to their environmentally benign nature, as oxidation can be achieved without the need for commonly used oxidizing agents. 2,2,6,6-Tetramethylpiperidinyloxyl radical commonly known as TEMPO is a stable aminoxyl radical utilized for the oxidation of various classes of alcohols to carbonyl compounds by using cyclic voltammetry. The present review focuses on the various electrochemical reactions utilizing TEMPO as a mediator such as the oxidative conversion of alcohols, carbohydrates, amines, sulphur-containing compounds, and alkenes in both laboratory as well as industrial scales and covers literature from 1950 till present date. The properties, reactivity, and yield percentages of these reactions would provide a basis for better electrocatalyst design in future studies involving TEMPO and its derivatives as mediators.

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Section: Tempo Mediated Electrochemical Oxidations Of Alkenesmentioning

confidence: 99%