ChemInform Abstract: Systematic Reactions of [Pt(PF₃)₄].

Abstract

Platinum I 8300 Systematic Reactions of [Pt(PF3)4]. -New Pt-PF3 compounds are synthesized and characterized by single crystal XRD, NMR, IR, and Raman spectroscopy, and ab initio MP2 calculations. (III) crystallizes in the cubic space group I43m (Z = 2), (IV) in the orthorhombic space group Pmmn (Z = 2), (V) in the triclinic space group P1 (Z = 4), (VI) in the orthorhombic space group Pbca (Z = 4), (VII) in the monoclinic space group P21/n (Z = 2), and (VIII) and [Pt(PF3)8H][AsF6]·2HF in the monoclinic space group C2/c (Z = 4). -(DREWS, T.; RUSCH, D.; SEIDEL, S.; WILLEMSEN, S.; SEPPELT*, K.; Chem. Eur.