Chemischer Informationsdienst
 1978
DOI: 10.1002/chin.197852321
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ChemInform Abstract: THE CHEMISTRY OF POLYNUCLEAR COMPOUNDS. PART 31. SYNTHESIS OF UNDECACARBONYLHYDRIDOTRIOSMATE(1‐) AND ITS REACTION WITH OCTADECACARBONYLHEXAOSMIUM TO GIVE A CARBOXYLATE‐BRIDGED ANIONIC ENNEAOSMIUM SPECIES

Colin R. Eady1,
Brian F. G. Johnson2,
Jack Lewis3
et al.

Abstract: Durch Umsetzung von O33‐ (CO)12 mit KOH in MeOH wird das Titelanion (I) erhalten, das mit Os6(CO)18 zu dem Anion (II) reagiert, in dem eine Os3‐ und eine Osö‐Einheit durch eine COg‐Gruppe verbunden sind.

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