ChemInform Abstract: THE FORMATION OF TIN(IV)‐MANGANESE CARBONYL CLUSTERS WITH OPEN AND CLOSED METAL‐METAL SKELETON BY REACTION OF TIN(II) HALIDES WITH DECACARBONYLDIMANGANESE
Abstract:Während die Umsetzung von Sn‐halogeniden mit Mn,(CO)," im Bombenrohr als Endprodukte die offenen Verbindungen (I) mit verzerrt tetraedrischer Koordination am Sn liefert, entstehen bei den gleichen Umsetzungen im druckentlasteten Schlenkrohr überwiegend die neuen Cluster (II).
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