ChemInform Abstract: The Mn(acac)₃‐RCN‐CCl₄ System as a New Efficient Reagent for the Oxidation of Secondary Alcohols into Ketones.

Abstract

The Mn(acac) 3 -RCN-CCl 4 System as a New Efficient Reagent for the Oxidation of Secondary Alcohols into Ketones. -Manganese compounds activated by nitriles efficiently catalyze the oxidation of various secondary alcohols into corresponding ketones in the presence of CCl 4 . The oxidation proceeds through the formation of alkyl hypochlorites generated from CCl 4 and the alcohols in the presence of the catalytic system. -(KHUS-NUTDINOV, R. I.; SCHADNEVA, N. A.; BAIGUZINA, A. R.; DZHEMILEV, U. M.; Russ.