ChemInform Abstract: The Preparation of Thiazyltrifluoromethane, CF3SN, the Hexachloro‐3‐cyclopentenylidenaminosulfides C5Cl6NSX (X: CF3, Cl, NSO, SCF3, C5Cl6N) and the Crystal Structures of C5Cl6NSX (X: CF3, Cl).

Abstract

Thermal decomposition of CF3‐S(Cl)=N‐SiMe3 is found to give oligomeric, possibly cyclic (CF3‐SN)x rather than monomeric CF3‐SN.