ChemInform Abstract: Thiazyl Trifluoride (NSF₃) Adducts and Imidodifluorosulfate (F₂OSN‐) Derivatives of Hg(OTeF₅)₂.

Abstract

Reactions of Hg(OTeF5)2 with excess amounts of NSF3 in SO2ClF or Freon‐114 (FEP reaction vessel, 0 °C, 2 d) result in the formation of NSF3 adducts of the compositions [Hg(OTeF5)2·NSF3]∞ (I), [Hg(OTeF5)2·2NSF3]2 (II), and Hg3(OTeF5)6·4NSF3 (III).