ChemInform Abstract: Thioetherification of Chloroheteroarenes: A Binuclear Catalyst Promotes Wide Scope and High Functional‐Group Tolerance.

Abstract

Scope and High Functional-Group Tolerance. -The nucleophilic substitution of a variety of chloro-and bromohetarenes with arylthiols is optimized to use [PdCl(allyl)] 2 in combination with a ferrocenyltetraphosphane as ligand. -(PLATON, M.; WIJAYA, N.; RAMPAZZI, V.; CUI, L.; ROUSSELIN, Y.; SAEYS, M.; HIERSO*, J.-C.; Chem. -Eur. J. 20 (2014) 39, 12584-12594, http://dx.doi.org/10.1002/chem.201403337 ; Inst. Chim. Mol., Univ. Bourgogne, F-21078 Dijon, Fr.; Eng.) -Mais 12-124