ChemInform Abstract: Triflic Acid‐Mediated Rearrangements of 3‐Methoxy‐8‐oxabicyclo[3.2.1]octa‐3,6‐dien‐2‐ones: Synthesis of Methoxytropolones and Furans.

Williams, Yvonne D.; Meck, Christine; Mohd, Noushad; Murelli, Ryan P.

doi:10.1002/chin.201419034

Search citation statements

Order By: Relevance

Paper Sections

Select...

Accepted Manuscript1

Citation Types

Supporting

Mentioning

Contrasting

Year Published

2022

Publication Types

Select...

Article1

Relationship

Self Cite0

Independent1

Authors

Journals

Cited by 1 publication

(1 citation statement)

References 1 publication

Supporting

Mentioning

Contrasting

Order By: Relevance

“…In certain cases more direct conversions of oxygen-bridged cycloheptadienones into tropolones can be achieved using triflic acid. 82 An ingenious amalgamation of two of the four basic approaches to troponoids shown in Figure 11 has been reported. 83 So, as outlined in Scheme 14, the Diels-Alder reaction of furan ( 103…”

Section: Accepted Manuscriptmentioning

confidence: 97%

Troponoid Compounds as Therapeutic Agents and as Targets and Templates for Chemical Synthesis

Tan

Chen

Lan

et al. 2022

Synlett

View full text Add to dashboard Cite

The renewed interest in troponoid compounds as potential therapeutic agents and the ongoing discovery of new, naturally-occurring and biologically active members of the class has resulted in an attendant focus on developing and deploying methods for their synthesis. This review highlights some of the significant recent developments in the area of troponoid chemistry that serve to contextualize our group’s longstanding and ongoing interest in the synthesis of such compounds through the cyclopropane-mediated ring-expansion of cyclohexanoid and benzenoid compounds. The various means by which such conversions can be accomplished and their application to the synthesis of both natural and non-natural troponoids are detailed.

show abstract

Section: Accepted Manuscriptmentioning

confidence: 97%