Chemischer Informationsdienst. Organische Chemie
 1971
DOI: 10.1002/chin.197147196
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ChemInform Abstract: UMLAGERUNGEN BEI DER ACYLIERUNG VON VICINALEN DIANIONEN

J. G. Smith1,
George Eric Simpson2

Abstract: Das aus Benzophenon‐anil (I) durch Reduktion mit Natrium erhaltene Dianion (II) setzt sich mit Chlorameisensäureäthylester (III) bei ‐60°C zum C‐Acyl‐Produkt (IV) um, das durch Wasser als Glycin‐Derivat (V) und durch Methyljodid (VI) als N‐Methyl‐glycinverbindung (VII) abgefangen werden kann.

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