ChemInform Abstract: UNSATURATED ALUMINUM ALKYLS. STABILIZATION AND REACTION WITH EPOXIDES

Abstract

Aus den Trialkylaluminiumverbindungen (I) entstehen mit Acetylen (II) die ungesättigten Vertreter (III), die mit Äthylenoxid (IV) über die Einschiebungsprodukte (V) zu den ungesättigten Carbinolen (VI) führen.

LiAlH4/silica chloride as a new chemoselective system for reduction of carbonyl compounds and phosphine oxides

“…Diisobutylaluminum hydride (DIBAL-H) and triisobutylaluminum hydride have found to be outstanding reductants for secondary phosphine oxides (SPOs) [6] and *Corresponding author. E-mail: m.khalilzadeh@hotmail.com triphenylphosphine oxide [7]. On the other hand, polymersupported reducing agents have received considerable attention in recent years and a variety of them, while exhibiting the advantages of polymeric reagents, have been used in the mild and selective reduction of organic compounds [8][9][10].…”