ChemInform Abstract: VOLTAMMETRIC INVESTIGATION OF THALLIUM ADSORPTION ON SILVER SINGLE CRYSTAL ELECTRODES

Siegenthaler, H.; Juettner, K.; Schmidt, Eberhard; Lorenz, W.J.

doi:10.1002/chin.197901020

Chemischer Informationsdienst

1979

DOI: 10.1002/chin.197901020

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ChemInform Abstract: VOLTAMMETRIC INVESTIGATION OF THALLIUM ADSORPTION ON SILVER SINGLE CRYSTAL ELECTRODES

H. Siegenthaler¹,

K. Juettner²,

Eberhard Schmidt³

et al.

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2015

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“…Surfaces such as Ag, Pt, and Au crystals are model catalysts and have proved rich in character for both experimental [11,12,13,14] and theoretical study [15,16,17,18]. The wide variety of acidic and basic electrolyte with and without additives such as halides [19,20,21], metal adsorption and deposition [22,23,24,25], and temperature effects [26,27] have made these some of most important surface systems studied to date.…”

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confidence: 99%

Charge-induced equilibrium dynamics and structure at the Ag(001)–electrolyte interface

Karl

Barbour

Komanicky

et al. 2015

Phys. Chem. Chem. Phys.

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The applied potential dependent rate of atomic step motion of the Ag(001) surface in weak NaF electrolyte has been measured using a new extension of the technique of X-ray Photon Correlation Spectroscopy (XPCS). For applied potentials between hydrogen evolution and oxidation, the surface configuration completely changes on timescales of 10(2)-10(4) seconds depending upon the applied potential. These dynamics, directly measured over large areas of the sample surface simultaneously, are related to the surface energy relative to over or under potential. Concurrent specular X-ray scattering measurements reveal how the ordering of the water layers at the interface correlates with the dynamics.

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mentioning

confidence: 99%

Charge-induced equilibrium dynamics and structure at the Ag(001)–electrolyte interface

Karl

Barbour

Komanicky

et al. 2015

Phys. Chem. Chem. Phys.

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ChemInform Abstract: VOLTAMMETRIC INVESTIGATION OF THALLIUM ADSORPTION ON SILVER SINGLE CRYSTAL ELECTRODES

Cited by 1 publication

References 1 publication

Charge-induced equilibrium dynamics and structure at the Ag(001)–electrolyte interface

Charge-induced equilibrium dynamics and structure at the Ag(001)–electrolyte interface

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