Chemischer Informationsdienst
 1980
DOI: 10.1002/chin.198044139
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ChemInform Abstract: α‐KETO DIANIONS. NEW REACTIVE INTERMEDIATES

Conrad J. Kowalski1,
M. Lynn O'Dowd2,
M. Carmel Burke3
et al.

Abstract: Das α‐Brom‐enolat (I) wird in 2 Stufen ‐ zunächst mit Methyl‐Li bei 0 °C in Ether, dann mit tert.‐Butyl‐Li bei ‐78°C ‐ zum Dianion (IIa) lithiiert, das durch Silylierung regioselektiv den Enolether (IIb) liefert.

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