Chemistry of trichlorosilane-tertiary amine combinations

Benkeser, Robert A.

doi:10.1021/ar50039a003

Cited by 129 publications

(59 citation statements)

References 52 publications

(16 reference statements)

Supporting

Mentioning

Contrasting

Unclassified

Order By: Relevance

“…The disadvantage of this process is the extreme reaction conditions. Utilising Benkeser reaction [44][45][46], a similar moiety (R 2 PSiCl 3 ) can be easily prepared with high yield at normal reaction conditions (Eq. (2.3)).…”

Section: Dialkylchalcogenophosphatesmentioning

confidence: 99%

Using coordination chemistry to develop new routes to semiconductor and other materials

Fan¹,

Afzaal²,

Mallik³

et al. 2007

Coordination Chemistry Reviews

131

View full text Add to dashboard Cite

Section: Dialkylchalcogenophosphatesmentioning

confidence: 99%

Using coordination chemistry to develop new routes to semiconductor and other materials

Fan¹,

Afzaal²,

Mallik³

et al. 2007

Coordination Chemistry Reviews

131

View full text Add to dashboard Cite

“…As a synthetic alternative to ''free'' SiCl 2 , the trichlorosilylation of related organic chlorides with HSiCl 3 in presence of amines (Benkeser reaction) [6] or halide ions [7] has made available a number of alkyltrichlorosilanes and bis-trichlorosilanes. By use of trimethylsilyltriflate as starting material, the HSiCl 3 /NEt 3 reagent has also been applied for Si-Si-bond formation [8].…”

Section: Dichlorosilylene Equivalentsmentioning

confidence: 99%

Dichlorosilylene and dichlorogermylene transfer to alkylidenephosphanes

Mont

Gust

Seppälä

et al. 2004

Journal of Organometallic Chemistry

View full text Add to dashboard Cite

“…The prep aration of bis(trichlorosilyl)methane by the reac tion of trichlorom ethane with trichlorosilane and a tertiary amine base [27] can be notably improved by replacing the trichlorom ethane with chloromethyltrichlorosilane or dichlormethyltrichlorosilane. The photo-chlorination of bis(trichlorosilyl)methane in CC14 solution is slow but proceeds with out side reactions, and the copper reduction of dichloro-bis(trichlorosilyl)methane at 160-190 °C affords 15 in 64% yield.…”

Section: Preparation O F C-halogenated Trichlorosilylethenesmentioning

confidence: 99%

Synthesis and Molecular Structure of Silylated Ethenes and Acetylenes

Rüdinger

Beruda

Schmidbaur

1994

Zeitschrift Für Naturforschung B

View full text Add to dashboard Cite

, By varying their stoichiometry these compounds can be used as single source feedstock gases for layers with tailor-made composition. In a new approach to the epitaxial deposition of silicon carbide, halogencontaining feedstock gases are expected to show improved properties owing to a greater reversi bility of the deposition process. W hereas polysilylalkanes halogenated at carbon are well rep resented in the literature [1 0 , 1 1 ], only limited information is available on the corresponding alkenes. The low thermal stability of polysilylated haloalkanes makes these compounds unsuitable for practical processes. The ethene analogues are expected to exhibit greater thermal stability and to be more amenable regarding storage and con * Reprint requests to Prof. Dr. H. Schmidbaur. tinuous handling. Although several sterically crowded polysilyl ethenes have been the subject of investigations of their molecular structure, dy namics and energy characteristics [12][13][14][15][16], the num ber of structurally characterized compounds is still small. Following work on silylalkanes, our more recent studies have therefore focused on silyl olefines. In the course of these investigations we have undertaken the X-ray structure determ i nations of bis(trichlorosilyl)acetylene and of the two most crowded trichlorosilylethenes, tris(trichlorosilyl)ethene and tetrakis(trichlorosilyl)-ethene.

show abstract

Chemistry of trichlorosilane-tertiary amine combinations

Cited by 129 publications

References 52 publications

Using coordination chemistry to develop new routes to semiconductor and other materials

Using coordination chemistry to develop new routes to semiconductor and other materials

Dichlorosilylene and dichlorogermylene transfer to alkylidenephosphanes

Synthesis and Molecular Structure of Silylated Ethenes and Acetylenes

Contact Info

Product

Resources

About