2018
DOI: 10.1002/ange.201810950
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Chemoselektive Pd‐katalysierte C‐TeCF3‐Kupplung von Aryliodiden

Abstract: Die TeCF3‐Gruppe zeigt vielversprechende Eigenschaften sowie Potential in einem weiten Bereich von Anwendungen, jedoch gibt es keine direkte Synthesemethode zu ihrer Einführung in aromatische Strukturen. Hier wird die erste direkte katalytische Methode zur Bildung von C(sp2)‐TeCF3‐Bindungen vorgestellt. Die Methode beruht auf einem Pd/Xantphos‐Katalysesystem und ermöglicht die Trifluormethyltellurolierung von Aryliodiden. Unsere rechnergestützten und mechanistischen Studien zeigen den Grund für die privilegier… Show more

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Cited by 8 publications
(2 citation statements)
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“…(5) Given the surge of interest within the synthetic community, the electrocatalytic trifluoromethylthiolation and trifluoromethylselenolation reactions are sure to provide further breakthroughs in the near future. (6) It is worth mentioned that Schoenebeck and co‐workers demonstrated the first direct catalytic methodology for the introduction of TeCF 3 in the presence of (Me 4 N)TeCF 3 in 2018 [57] . By extension, impacted by the fluorine atom, we envision that the functionality of the last remaining trifluoromethylchalcogen group TeCF 3 is similar to SCF 3 group in its great potential for materials, pharmaceutical as well as biochemical applications.…”
Section: Discussionmentioning
confidence: 97%
See 1 more Smart Citation
“…(5) Given the surge of interest within the synthetic community, the electrocatalytic trifluoromethylthiolation and trifluoromethylselenolation reactions are sure to provide further breakthroughs in the near future. (6) It is worth mentioned that Schoenebeck and co‐workers demonstrated the first direct catalytic methodology for the introduction of TeCF 3 in the presence of (Me 4 N)TeCF 3 in 2018 [57] . By extension, impacted by the fluorine atom, we envision that the functionality of the last remaining trifluoromethylchalcogen group TeCF 3 is similar to SCF 3 group in its great potential for materials, pharmaceutical as well as biochemical applications.…”
Section: Discussionmentioning
confidence: 97%
“…(6) It is worth mentioned that Schoenebeck and co-workers demonstrated the first direct catalytic methodology for the introduction of TeCF 3 in the presence of (Me 4 N)TeCF 3 in 2018. [57] By extension, impacted by the fluorine atom, we envision that the functionality of the last remaining trifluoromethylchalcogen group TeCF 3 is similar to SCF 3 group in its great potential for materials, pharmaceutical as well as biochemical applications. Evidently, it is significant to explore the chemical properties of (Me 4 N)TeCF 3 in organic synthesis while it presents an efficient reagent to synthesize elaborated CF 3 Te-compounds.…”
Section: Discussionmentioning
confidence: 99%