Kirkby [Band 117 and increasing pH. CEC, was highest with WAI ratios of 1.8, when the synthetic preparations were carried out at pH 8.3 and highest with Si/Al ratios of 3.5 at p H 5.CEC, generally increased with increasing Si/AI ratios, while CEC, on the otherhand decreased. The predominant charge on "ageing" for 10 days at p H 2 was CEC,. This was virtually independent of the Si/Al ratios.The aluminosilicates failed to form coarse precipitates when the Si/Al ratios exceeded 1.8 at pH's of 5, 7 and 8.3 !unless alkaline earth salts (BaCl,, CaCI, or MgCI,) were added. Preliminary acidification of the sodium silicate or, in the presence of excess AlCI,, titration with N a O H led to coarse precipitates in the absence of alkaline earth salts.Aluminosilicates prepared from metasilicate(Na,SiO,) had predominantely variable charges. "Ageing" prior to titration had little influence on the ratio of CEC, to CEC,. Acidification and "ageing" of AICI, and Na,Si,O, prior to titration gave rise principally to CEC,.The significance between CEC, and CEC, in relation to the effectiveness of synthetic aluminosilicates as cracking catalysts has been discussed. The desirability of colloids possessing largely CEC, and therefore high acidic properties, resulting from "ageing" have been pointed out. Certain factors involving CEC, and CEC, in relation to natural clay formation in soils have (been discussed.[3211]