Three naturally and six mechanically ventilated microenvironments (MEs) of a mixed use commercial building in Delhi are used to study indoor-outdoor (I/O) relationships of particulate matter ≤10µm (PM 10 ), ≤2.5µm (PM 2.5 ) and ≤1µm (PM 1 ). Effect of environmental and occupancy parameters on the concentrations of PM during working and non-working hours (i.e. activity and non-activity periods, respectively) are also investigated. Average outdoor concentration of PM 10 and PM 2.5 were found to exceed the 24 hour averaged national standard values, showing a polluted environment surrounding the studied building. During the working hours, indoor PM 10 concentration was found 6-10 times, both PM 2.5 and PM 1 were 1.5-2 times, higher than the non-working hours in the selected MEs. The variations of indoor concentrations were highest (17.1-601.2 µg/m 3 ) for PM 10 compared with PM 2.5 (16.9-102.6 µg/m 3 ) and PM 1.0 (10.6-63.6 µg/m 3 ). The I/O for PM 10 , PM 2.5 and PM 1.0 varied from 0.37-3.1, 0.2-3.2 and 0.17-2.9, respectively. The results suggest highest I/O for PM 10 , PM 2.5 and PM 1 as 3.1, 2.15 and 1.76, respectively, in all the three natural ventilated MEs (canteen, kitchen, reception). Irrespective of PM types, the average I/O was <1 for mechanically ventilated MEs compared with >1 for naturally ventilated MEs. As opposed to PM 1 , better correlation (r >0.6) was noted between indoor PM 10 , PM 2.5 and CO 2 concentrations in most of the airtight MEs.