2024
DOI: 10.1002/ange.202400502
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Chiral CpxRhodium(III)‐Catalyzed Enantioselective Aziridination of Unactivated Terminal Alkenes

Juanjuan Wang,
Mu‐Peng Luo,
Yi‐Jie Gu
et al.

Abstract: Chiral cyclopentadienyl‐rhodium(III) CpxRh(III) catalysis has been demonstrated to be competent for catalyzing highly enantioselective aziridination of challenging unactivated terminal alkenes and nitrene sources. The chiral CpxRh(III) catalysis system exhibited outstanding catalytic performance and wide functional group tolerance, yielding synthetically important and highly valuable chiral aziridines with good to excellent yields and enantioselectivities (up to 99% yield, 93% ee). This protocol presents a nov… Show more

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