Conventional three-dimensionally (3D) chiral media can exhibit optical activity for transmitted waves, but optical activity for reflected waves is negligible. This work shows that mirror asymmetry of the experimental arrangement -extrinsic 3D chirality -leads to giant optical activity for reflected waves with fundamentally different characteristics. It is demonstrated experimentally that extrinsically 3D-chiral illumination of a lossy metasurface backed by a mirror enables tunable circular dichroism and circular birefringence as well as perfect absorption of circularly polarized waves. In contrast, such polarization phenomena vanish for conventional optically active media backed by a mirror.Optical activity, that is rotation of the polarization state of light (circular birefringence) and differential absorption of circularly polarized waves (circular dichroism), is a well-known consequence of transmission through chiral media. It is usually observed in intrinsically 3D-chiral structures, i.e. structures that cannot be superimposed with their mirror image (Fig. 1a). Large polarization changes occur for transmission through 3D-chiral metamaterials, 1-7 and natural media 8 where effects can accumulate over long interaction lengths. In contrast, circular birefringence and dichroism for waves reflected from 3D-chiral solids and liquids are usually negligible.
9-12It is less well-known that optical activity also occurs in achiral structures, if the direction of the wave incident onto the material makes the experimental arrangement different from its mirror image (Fig. 1b). This is known as extrinsic 3D chirality and leads to large circular birefringence and dichroism for both transmitted [13][14][15][16][17] and reflected 18 waves as well as similar phenomena for scattering 19 and second harmonic generation 20 by nanostructures. Extrinsic 3D chirality is present for oblique incidence onto structured interfaces (e.g. planar metamaterials also known as metasurfaces) that lack two-fold rotational symmetry, if the structure does not have a line of mirror symmetry in the plane of incidence. Other forms of extrinsic chirality resulting in directionally asymmetric transmission 21 and different photoluminescence 22 for opposite circular polarizations have also been reported. This letter demonstrates a fundamental difference between optical activity due to intrinsic and extrinsic 3D chirality. Polarization changes due to intrinsic 3D chirality will be reversed if the electromagnetic wave is reflected back through the 3D-chiral medium. In contrast, polarization changes due to extrinsic 3D chirality will not vanish under the same circumstances, providing an opportunity to tune specular optical activity and to realize perfect absorbers for circularly polarized waves. Figure 1c,d illustrates why placing an optically active medium in front of a mirror will lead to vanishing a) Electronic mail: erp@orc.soton.ac.uk; www.nanophotonics.org.uk and enhanced optical activity in case of intrinsic and extrinsic 3D chirality, respectively. A...