2024
DOI: 10.1021/acsmacrolett.4c00122
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Chiral Transfer of Linear Polysiloxane with Preferred-Handed Helical Conformation

Tomoki Mure,
Yakumo Kinoshita,
Hinari Sakai
et al.

Abstract: We report the preparation of chiral silica using a linear polysiloxane main chain with a preferred-handed helical structure as the template. Poly(methylvinyl siloxane) (PMVS) with a cysteine derivative side chain designated as PMVS-Cys was prepared using anionic polymerization and an ene-thiol reaction. PMVS-Cys forms a helical conformation in both solution and film via hydrogen bonding between amide groups at side chains. The helical structure remains during the calcination process, resulting in silica with h… Show more

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