2017
DOI: 10.1098/rsta.2015.0433
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Chirality and the angular momentum of light

Abstract: Chirality is exhibited by objects that cannot be rotated into their mirror images. It is far from obvious that this has anything to do with the angular momentum of light, which owes its existence to rotational symmetries. There is nevertheless a subtle connection between chirality and the angular momentum of light. We demonstrate this connection and, in particular, its significance in the context of chiral light–matter interactions.This article is part of the themed issue ‘Optical orbital angular momentum’.

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Cited by 53 publications
(43 citation statements)
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References 97 publications
(229 reference statements)
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“…A dramatic demonstration of this is provided through the entanglement of OAM [54]. The OAM of light is manifest in the interaction between light and matter and we include two papers covering this aspect of the field: one describing the interaction with atoms [55] and one addressing the interaction with chiral objects, particularly chiral molecules [56]. The study of orbital angular momentum has had an impact beyond the field of optics and an issue devoted to OAM would not be complete without papers looking beyond optics.…”
Section: Recent Developments and This Theme Issuementioning
confidence: 99%
“…A dramatic demonstration of this is provided through the entanglement of OAM [54]. The OAM of light is manifest in the interaction between light and matter and we include two papers covering this aspect of the field: one describing the interaction with atoms [55] and one addressing the interaction with chiral objects, particularly chiral molecules [56]. The study of orbital angular momentum has had an impact beyond the field of optics and an issue devoted to OAM would not be complete without papers looking beyond optics.…”
Section: Recent Developments and This Theme Issuementioning
confidence: 99%
“…In contrast, natural Rayleigh optical activity has been reported for a handful of large chiral biological structures, including octopus sperm [35], but has thus far proved elusive for small chiral molecules [2], in spite of potential applications such as the robust assignment of absolute configuration [36]. The difficulties here might be partially overcome using structured light [37,38]. Interestingly, orientated achiral molecules can also exhibit natural optical activity via the first-order correction, embodied by the s (1) ξ [2], and partially orientated chiral molecules can exhibit natural optical activity via the zeroth-order theory, embodied by the s (0) ξ [39].…”
Section: General Calculationmentioning
confidence: 98%
“…Illumination by more exotic forms of light could open the door to new possibilities, one example of which is highlighted in section IV. Evanescent fields play important roles in scattering-type near-field optical microscopy techniques [10] and it has recently been shown that illumination by standing waves yields new possibilities for optical activity [37,38], to give two more examples of non-plane-wave illumination in light scattering.…”
Section: General Calculationmentioning
confidence: 99%
“…The beams with polarization singularities are used in engineering the point spread function for imaging [16] and to enhance the sensitivity in polarimetry methods [17], etc., to name a few [18]. Continuing investigation of optical fields embedded with both type of singularities has initiated new fields of study in optical physics like spin-orbit coupling [19], spin and orbital Hall effect [20,21], chiral light matter interactions [22] to give some examples from a long list.…”
Section: Introductionmentioning
confidence: 99%