We investigate the confined states and transport of three-dimensional Weyl electrons around a onedimensional external rectangular electrostatic potential. Confined states with finite transverse wave vector exist at energies higher than the half well depth or lower than the half barrier height. The rectangular potential appears completely transparent to normal incident electrons but not otherwise. The tunneling transmission coefficient is sensitive to their incident angle and shows resonant peaks when their energy coincides with the confined spectra. In addition, for electrons in the conduction (valence) band through a potential barrier (well), the transmission spectrum has a gap of width increasing with the incident angle. Interestingly, the electron linear zero-temperature conductance over the potential can approach zero when the Fermi energy is aligned to the top and bottom energies of the potential, when only electron beams normal to the potential interfaces can pass through. The considered structure can be used to collimate Weyl electron beams.In the standard picture a topologically-nontrivial phase of matter corresponds to gapped bulk materials with topologically protected gapless surface/edge states [1,2]. Recent work has shown, however, that certain gapless systems may also be topologically nontrivial which are known as topological semimetals [3][4][5][6][7][8]. They arise from the existence of band-touching points (Weyl nodes) in their electronic structure. Their properties become particularly striking when the Fermi energy approaches the Weyl nodes at which a linear energy dispersion in three dimensions exists.Weyl semimetal (WSM) is one of the topological semimetals which embeds splitting Weyl nodes without other degeneracy by breaking time-reversal symmetry or spatial inversion symmetry [9]. Theoretically, a Weyl node can be modeled as a magnetic monopole in momentum space which cannot exist independently. Therefore, the Weyl nodes occur always in pairs with opposite chirality and consequently the Fermi arc states emerge on the surface [9][10][11][12]. Due to these unique characteristics, WSMs can show various exotic phenomena, such as transport anomaly [13][14][15] However, there are two Weyl fermions with opposite chiralities in each Weyl node of Dirac semimetals due to the presence of both time reversal and inversion symmetry. The non-degeneracy of the intersecting bands in WSMs warrants a topological stability of the Weyl nodes, which hold advantage for possible practical applications in nanodevices. Such a unique electronic system has been a particularly attractive platform for investigation of various electric and optical properties. The appearance of Weyl nodes will generate negative magnetoresistance related to chiral anomaly under the presence of parallel magnetic and electric fields [37]. A number of compelling observations have been made recently [25,38,39].Effective electric field or electrostatic potential can be established in binary/trinary materials using the band engineering methods. ...