Chloride Ion Battery Review: Theoretical Calculations, State of the Art, Safety, Toxicity, and an Outlook towards Future Developments

Gschwind, Fabienne; Euchner, Holger; Rodriguez-García, Gonzalo

doi:10.1002/ejic.201700288

Cited by 61 publications

(59 citation statements)

References 73 publications

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“…Transition‐metal and some main‐group‐metal halides/oxyhalides and chloride ion‐doped conducting polymer materials have been tested as the cathode materials in HIBs. The fundamentals, advantages, and safety concerns of HIBs and their electrode materials have been reviewed by Gschwind et al . In this section, we present an overview of the state of the art HIBs in terms of key advances and challenges.…”

Section: Halide‐ion Batteriesmentioning

confidence: 99%

“…Thec ombination of these metals with elements such as Fa nd Cl that have ah igh electronegativity can also yield large Gibbs-free energies,and thus large EMF values.Analternative approach to obtaining high energy densities has been the development of rechargeable batteries based on F À or Cl À anion transfer,n amely, halide-ion batteries (HIBs). [16,20] Besides the alkali and alkaline-earth metals,r are-earth metals such as La and Ce have also been considered as anode materials for HIBs because of their low standard electrode potentials and high theoretical volumetric capacities.T ransition-metal and some main-group-metal halides/oxyhalides and chloride ion-doped conducting polymer materials have been tested as the cathode materials in HIBs.T he fundamentals,a dvantages,a nd safety concerns of HIBs and their electrode materials have been reviewed by Gschwind et al [40,291] In this section, we present an overview of the state of the art HIBs in terms of key advances and challenges.…”

Section: Halide-ion Batteriesmentioning

confidence: 99%

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Halide‐Based Materials and Chemistry for Rechargeable Batteries

et al. 2020

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Rechargeable batteries are considered one of the most effective energy storage technologies to bridge the production and consumption of renewable energy. The further development of rechargeable batteries with characteristics such as high energy density, low cost, safety, and a long cycle life is required to meet the ever‐increasing energy‐storage demands. This Review highlights the progress achieved with halide‐based materials in rechargeable batteries, including the use of halide electrodes, bulk and/or surface halogen‐doping of electrodes, electrolyte design, and additives that enable fast ion shuttling and stable electrode/electrolyte interfaces, as well as realization of new battery chemistry. Battery chemistry based on monovalent cation, multivalent cation, anion, and dual‐ion transfer is covered. This Review aims to promote the understanding of halide‐based materials to stimulate further research and development in the area of high‐performance rechargeable batteries. It also offers a perspective on the exploration of new materials and systems for electrochemical energy storage.

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Section: Halide‐ion Batteriesmentioning

confidence: 99%

Section: Halide-ion Batteriesmentioning

confidence: 99%

Halide‐Based Materials and Chemistry for Rechargeable Batteries

et al. 2020

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“…

Chloride ion batteries (CIBs) are a promising type of energy storage device due to their high theoretical volumetric energy density and abundant reserves of chlorine-containing precursors. [11] In addition, the abundance of chloride-containing materials and their availability worldwide not only lower the costs but also enable manufacturing all over the world. In this work, layered double hydroxides (LDHs), which consist of a trimetallic NiVAl hydroxide host matrix and interlayer Cl − , are demonstrated to be high-performance cathode materials for CIBs.

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mentioning

confidence: 99%

Ultralong‐Life Chloride Ion Batteries Achieved by the Synergistic Contribution of Intralayer Metals in Layered Double Hydroxides

Yin

Luo

Zhang

et al. 2019

Adv Funct Materials

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Chloride ion batteries (CIBs) are a promising type of energy storage device due to their high theoretical volumetric energy density and abundant reserves of chlorine-containing precursors. However, the unsatisfactory cycling performance and structural instability of cathode materials hinder their practical application. In this work, layered double hydroxides (LDHs), which consist of a trimetallic NiVAl hydroxide host matrix and interlayer Cl − , are demonstrated to be high-performance cathode materials for CIBs. The Ni 2 V 0.9 Al 0.1 -Cl LDH is capable of delivering a high initial capacity of 312.2 mAh g −1 at 200 mA g −1 and an ultralong life over 1000 cycles (with a capacity higher than 113.8 mAh g −1 ). Such a long cycling life exceeds that of any reported CIBs. The remarkable Cl − -storage performance of the Ni 2 V 0.9 Al 0.1 -Cl LDH is ascribed to the synergetic contributions from V m+ (high redox activity), Ni 2+ (favorable electronic structure), and inactive Al 3+ (enhances the structural stability), which is revealed by a comprehensive study that utilizes synchrotron X-ray absorption near-edge structure experiments, kinetic investigations, and theoretical calculations. This study provides an effective strategy to achieve superior rechargeable batteries, which are applicable to large-scale energy storage and power grids.room-temperature chloride ion batteries (CIBs) based on Cl − shuttling [6][7][8][9][10] have attracted intensive attention as a result of their large theoretical volumetric energy density (up to 2500 Wh L −1 ). [11] In addition, the abundance of chloride-containing materials and their availability worldwide not only lower the costs but also enable manufacturing all over the world. Another key advantage of CIBs is their dendritefree feature, which is derived from the simple migration of Cl − , making CIB systems more secure and suitable for large-scale energy storage. [12] Since the first proof that the reversible shuttle of chloride ions between a metal chloride cathode (BiCl 2 , CoCl 2 , and VCl 3 ) and a lithium anode was proposed by Zhao et al., [5] metal oxychlorides [6,13] and chloride-doped organic polymers, [14,15] such as PPy and PANI, have been subsequently demonstrated as possible electrode materials in CIBs. Although some progress has been made in CIB cathode materials during the past few years, it is still at the initial stage compared with the development of metal-ion batteries. One urgent issue to be solved is their short cycling life; i.e., most of these cathode materials can only sustain dozens of charge/discharge cycles with a moderate capacity of ≈40−100 mAh g −1 . Therefore, exploiting suitable Cl − -hosting cathode materials with a simultaneous high capacity and long cycling life is a top priority for the development of rechargeable CIBs.Layered double hydroxides (LDHs), whose structure can be generally expressed by the formula [M II 1−x M III x (OH) 2 ] (A n− ) x/n ·mH 2 O (M II and M III are divalent and trivalent metals respectively, and A n− is an interlayer anion co...

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“…[16] In this study,w ee lectrostatically immobilized [Fe(CN) 6 ] 3À/4À in a nonconducting amine-functionalized PSQ filmf or energy storage applications. [18][19][20][21][22] Nowadays, anionbased batteries such as F À , [23] BF 4 À [24] and Cl À [25][26][27][28] ionb attery has been explored for future electronic applications. [17] Thereafter,afew reports have concerned this type of redox polymer materials with regards to their basic electrochemical performance and their applications in H 2 O 2 reduction,biomoleculedetection, and its catalytic ascorbica cid oxidation, for example.…”

mentioning

confidence: 99%

“…[17] Thereafter,afew reports have concerned this type of redox polymer materials with regards to their basic electrochemical performance and their applications in H 2 O 2 reduction,biomoleculedetection, and its catalytic ascorbica cid oxidation, for example. [18][19][20][21][22] Nowadays, anionbased batteries such as F À , [23] BF 4 À [24] and Cl À [25][26][27][28] ionb attery has been explored for future electronic applications. To this end, we developed an anion (Cl À and NO 3 À )-based rechargeable aqueous battery by using ferrocyanidei mmobilized in a PSQ film.…”

mentioning

confidence: 99%

Flexible Anion Microbatteries: Towards Construction of a Hybrid Battery–Capacitor Device

Silambarasan

Joseph

2018

ChemSusChem

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A proof-of-principle study is presented on the rechargeable anion storage capability of ferrocyanide immobilized in a polysilsesquioxane (PSQ)-modified flexible/rigid film for aqueous battery applications. This electrode material delivers high power density up to 140 μWh cm and energy density of 9.4 μWh cm with a long cycle life of more than 200 cycles in chloride ion medium. The proposed energy storage mechanism of this system is based on insertion and extraction of the anion into the [Fe(CN) ] -PSQ film during charging and discharging processes, respectively. Moreover, a hybrid battery-capacitor device comprising a graphite rod (capacitor) and the ferrocyanide-immobilized PSQ film as a faradaic electrode shows enhanced electrochemical performance.

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Chloride Ion Battery Review: Theoretical Calculations, State of the Art, Safety, Toxicity, and an Outlook towards Future Developments

Cited by 61 publications

References 73 publications

Halide‐Based Materials and Chemistry for Rechargeable Batteries

Halide‐Based Materials and Chemistry for Rechargeable Batteries

Ultralong‐Life Chloride Ion Batteries Achieved by the Synergistic Contribution of Intralayer Metals in Layered Double Hydroxides

Flexible Anion Microbatteries: Towards Construction of a Hybrid Battery–Capacitor Device

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