2022
DOI: 10.26434/chemrxiv-2022-5zgfd
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Chlorination of Hydrogenated Silicon Nanosheets Revealed by 1H{35Cl} and 29Si{35Cl} Solid-State NMR Spectroscopy

Abstract: Two-dimensional silicon nanosheets (Si-NS) synthesized by topotactic deintercalation of CaSi2 are hypothesized to consist of buckled layers of sp3 hybridized silicon atoms that are bonded to three other framework Si atoms and a terminal atom or functional group such as H, Cl or an -OH group. Here, we apply 1H{35Cl} and 29Si{35Cl} Reso-nance-Echo Saturation-Pulse DOuble-Resonance (RESPDOR) solid-state NMR experiments to directly confirm the presence of chlorinated Si atoms within Si-NS. Plotting the observed 1H… Show more

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