2022
DOI: 10.1016/j.jes.2022.04.029
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Chlorination of para-substituted phenols: Formation of α, β-unsaturated C4-dialdehydes and C4-dicarboxylic acids

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Cited by 11 publications
(2 citation statements)
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“…Over the range of added [Br], bromine recovery as THMs from paraben precursors declined by a factor of 2 while that of salicylates increased by a factor of nearly 50 (Figure B). Precursors that readily undergo ring cleavage such as parabens may present less evidence of ipso substitution if aromaticity is required for substitution to occur . However, at [Br] <10 μM, bromine recovery as THMs from parabens exceeded that of salicylates.…”
Section: Resultsmentioning
confidence: 99%
See 1 more Smart Citation
“…Over the range of added [Br], bromine recovery as THMs from paraben precursors declined by a factor of 2 while that of salicylates increased by a factor of nearly 50 (Figure B). Precursors that readily undergo ring cleavage such as parabens may present less evidence of ipso substitution if aromaticity is required for substitution to occur . However, at [Br] <10 μM, bromine recovery as THMs from parabens exceeded that of salicylates.…”
Section: Resultsmentioning
confidence: 99%
“…Precursors that readily undergo ring cleavage such as parabens may present less evidence of ipso substitution if aromaticity is required for substitution to occur. 42 However, at [Br] <10 μM, bromine recovery as THMs from parabens exceeded that of salicylates. The average recovery of bromine as THMs from paraben precursors was 4.4% from 1−10 μM added Br, while salicylate precursors had an average bromine recovery of 1.5% over the same range.…”
Section: Parallel Experiments With Salicylatesmentioning
confidence: 99%