Chlorobenzene Mineralization Using Plasma/Photocatalysis Hybrid Reactor: Exploiting the Synergistic Effect

Abstract

Mineralization of gaseous chlorobenzene (major VOC from cement plants) was studied in a continuous reactor using three advanced oxidation processes: (i) photocatalysis, (ii) Dielectric Barrier Discharge (DBD) plasma and (iii) DBD/TiO2-UV coupling. The work showed an overproduction of OH * and O * radicals in the reaction medium due to the interaction of Cl * and O3. A parametric study was carried out in order to determine the evolution of the removal efficiency as a function of the concentration, the flow rate and the applied voltage. Indeed, a variation of the flow rate from 0.25 to 1 m3/h resulted in a decrease in the degradation rate from 18 to 9%. Similarly, an increase in concentration from 13 to 100 mg/m3 resulted in a change in degradation rate from 18 to 4%. When the voltage was doubled from 6 to 12 kV, the degradation rate varied from 22 to 29 % (plasma) and from 53 to 75% (coupling) at 13 mg/m3. The evolution of COX and O3 was monitored during the experiments. When the voltage was doubled, the selectivity increased from 28 to 37% in the plasma alone and from 48 to 62 % in the coupled process. In addition, at this same voltage range, the amount of ozone formed varied from 10 to 66 ppm in plasma and 3 to 29 ppm in coupling. This degradation performance can be linked to a synergistic effect, which resulted in an increase in the intensity of the electric field of plasma by the TiO2 and the improvement in the performance of the catalyst following the bombardment of various high-energy particles of the plasma.

Kinetic Modeling of the Photocatalytic Degradation of Chlorinated Aromatic Volatile Organic Compounds: Mass Transfer Enhancement

“…Photocatalysis generally proceeds in three steps: the mass transfer of the pollutant to the catalyst, the adsorption on the catalyst, and the chemical reaction. Among continuous photocatalytic reactors, tangential flow configurations, which consider the VOC concentration, UV intensity, and water vapor composition, offer adaptability to an industrial scale [22]. The desorption and diffusion processes of VOCs and their by-products are typically negligible, and steady-state kinetic models often overlook the mass transfer effects.…”

Catalysts for Air Pollution Control: Present and Future

“…Photocatalysis is another interesting method for eliminating chlorobenzene. To this end, Aly Koné et al [11] used a plasma/photocatalysis hybrid reactor. The mineralization of gaseous chlorobenzene was comparatively studied in a continuous reactor using three advanced oxidation processes: (i) photocatalysis, (ii) dielectric barrier discharge (DBD) plasma, and (iii) DBD/TiO2-UV coupling.…”