Chloroperoxidase Catalyzed Enantioselective Epoxidation of Selected Olefins and Regiospecific Degradation of Dimethylsulfoniopropionate

Investigating the Role of the Proximal Cysteine Hydrogen Bonding Network and Distal Pocket in Chloroperoxidase

“…The elution order of the column tends to be the (R)-enantiomer then followed by the (S)-enantiomer as the retention time of the (R)-configuration is shorter than that of the (S)-configuration in Whelk-O 1 column. This elution order of the enantiomers was confirmed previously in our lab through the (R)-and (S)-styrene oxide standards [140].…”