Chlorure et bromure de cuivre(I)-benzonitrile

Abstract

Abstract. CuX. C6HsCN, (X=CI, Br) : CuC1. C6HsCN.

A Polymeric Structure Containing Cu2Cl2 Units Bridged by 4,4‘-Bipyridine: (PPh3)2Cu2(μ-Cl)2(μ-4,4‘-bipyridine)

“…A series of Cu(I) compounds with chain structures containing Cu 2 Cl 2 dimers and with the general composition CuCl·L (where L = CH 3 CN, C 6 H 5 CN, quinoline C 9 H 7 N, pyridine) have also been reported. Each of these compounds contains Cu 2 Cl 2 dimers that are linked into an infinite chain by sharing the Cl atoms between dimers.…”

Lewis base adducts of Group 11 metal(I) compounds. Part 36. The synthesis and X-ray crystallographic characterisation of polymeric copper(I) iodide–benzonitrile (2/1)

“…As expected, the geometries around the copper atoms are not unusual. It is worth noting, however, that, as for 1 04.00 ( 7) I( 4) CU(3)CU( 4) Cu( 3)CU(4"') Cu( 4)C u( 4"') 109.9(3) 11 1.1(3) 1 10.4(3) 1 13.84 (7) 98.31(8) 1 12.69 (8) 65.07 (7) 67.3 1 (7) 1 00.4 1 (7) [(CuI),(2Me-py)], the two p4 iodide atoms exhibit marginally longer I-Cu distances on average than the two p3 atoms: Additional material available from the Cambridge Crystallographic Data Centre comprises H-atom co-ordinates, thermal parameters, and remaining bond lengths and angles.…”

Metal halide, nitrile, antimony pentachloride complexes. I. Tetrakis(benzonitrile)copper(I) hexachloroantimonate(V) and hexakis(benzonitrile)copper(II) bis[hexachloroantimonate (V)]

“…The crystal structures for binary adducts of cuprous chloride with acetonitrile or benzonitrile have been determined (12,13).…”