Diffusion‐Controlled Solid State Reactions 2010
DOI: 10.1002/9783527631025.ch12
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Choice of Optimal Regimes in Cellular Decomposition, Diffusion‐Induced Grain Boundary Migration, and the Inverse Diffusion Problem

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“…Lyashenko [15] emphasized a good correlation between the calculated and experimental parameters of DP reaction. However, the calculated concentration change across the α lamella for the Pb-15at.% Sn alloy corresponds to extremely thin lamella (50 nm) which is highly unrealistic because the same Author provides 120 nm as a typical value of the interlamellar distance.…”
Section: New Theories and Modelsmentioning
confidence: 99%
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“…Lyashenko [15] emphasized a good correlation between the calculated and experimental parameters of DP reaction. However, the calculated concentration change across the α lamella for the Pb-15at.% Sn alloy corresponds to extremely thin lamella (50 nm) which is highly unrealistic because the same Author provides 120 nm as a typical value of the interlamellar distance.…”
Section: New Theories and Modelsmentioning
confidence: 99%
“…Lyashenko [15] proposed model of the DP using a set of equations for the (i) mass transfer in the moving interphase boundary, (ii) balance of the entropy fluxes at the phase transformation front, and (iii) maximum rate of the free energy release. The use of the principle of maximum rate of free energy release and balance of entropy fluxes allowed an independent determination of the main parameters, including the interlamellar distance, the maximum velocity of the phase transformation front, and the concentration jump at this boundary.…”
Section: New Theories and Modelsmentioning
confidence: 99%