Hydrophobic and breathable nanofiber membranes have attracted
considerable
attention owing to their applications in various fields. In this study,
we fabricated superhydrophobic and breathable nanofiber membranes
using solution blow spinning. We optimized the spinning process parameters
by analyzing their effects on the structure and properties of the
nanofiber membranes. And the nanofiber membranes achieved superhydrophobicity
through hydrophobic modification treatment. The average fiber diameter
and pore size of the obtained membrane were 0.51 and 13.65 μm,
respectively. The membranes exhibited superhydrophobicity, breathability,
and mechanical properties: water vapor transmission of 12.88 kg/m
2
/day, air permeability of 10.97 mm/s, water contact angle
of 150.92°, maximum tensile stress of 5.36 MPa, and maximum elongation
at break of 12.27%. Additionally, we studied the impact of heat treatment
on the nanofiber membranes. The membranes prepared in this study can
be applied to protective garments, outdoor clothing, antifouling materials,
etc. Because of its relatively higher production efficiency, solution
blow spinning is a prospective method for producing functional nanofibers.