Finding families that admit a linear χ-binding function is a problem that has interested researchers for a long time. Recently, the question of finding linear subfamilies of 2K 2 -free graphs has garnered much attention. In this paper, we are interested in finding a linear subfamily of a specific superclass of 2K 2 -free graphs, namely (P 3 ∪ P 2 )-free graphs. We show that the class of {P 3 ∪ P 2 , gem}-free graphs admits f = 2ω as a linear χ-binding function.Furthermore, we give examples to show that the optimal χ-binding function f * ≥ 5ω(G) 4 for the class of {P 3 ∪ P 2 , gem}-free graphs and that the χ-binding function f = 2ω is tight when ω = 2 and 3.