Chromium doping into NASICON-structured Na3V2(PO4)3 cathode for high-power Na-ion batteries

Lee, Jun; Park, Sohyun; Park, Young; Song, Jinju; Sambandam, Balaji; Mathew, Vinod; Hwang, Jang Yeon; Kim, Jaekook

doi:10.1016/j.cej.2021.130052

Cited by 79 publications

(42 citation statements)

References 67 publications

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“…However, owing to its limited resources accounting for only 0.0065% of the earth's crust, the focus has shifted to Sodium (Na) replacement in place of Li to develop low-cost and sustainable batteries. [14][15][16][17][18][19] Na displays similar physical and electrochemical features as Li. [20][21][22] Over the years, much research has been carried out to make battery materials that can provide high performance, decrease the cost of production, and make the fabrication processes simpler.…”

mentioning

confidence: 92%

“…The first Lithium (Li) ion battery was commercialized in 1991 13 and has transformed the modern world. However, owing to its limited resources accounting for only 0.0065% of the earth's crust, the focus has shifted to Sodium (Na) replacement in place of Li to develop low‐cost and sustainable batteries 14‐19 . Na displays similar physical and electrochemical features as Li 20‐22 .…”

Section: Introductionmentioning

confidence: 99%

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Utilization of symmetric electrode materials in energy storage application: A review

Moossa

Abraham

Kahraman

et al. 2022

Intl J of Energy Research

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The development of efficient energy storage systems is an important field of research in the modern era where fossil fuels are headed toward depletion. The invention of batteries is regarded as one of the most significant advancements in the field of energy storage. From its inception, a lot of research has been done and is still being carried out to develop novel and advanced materials that provide improved performance in terms of capacity, stability, and cost. In this context, symmetric or bipolar electrodes, which utilize the same material for the anode and the cathode, emerge as a suitable solution for battery technology. In this work, different types of symmetric electrode materials for batteries are subjected to review. The various structures, methods of synthesis, and characteristics are analyzed and presented. The Na 3 V 2 (PO 4 ) 3 (NVP) is the most widely analyzed symmetric material among all the symmetric materials. The Na-based systems are widely studied in symmetric configurations for their resource availability and price economics advantages. Aqueous and solid-state symmetric batteries are the emerging systems in symmetric batteries. This review will provide insights to battery researchers involved in bipolar material design and shed light on new emerging energy storage techniques.

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mentioning

confidence: 92%

Section: Introductionmentioning

confidence: 99%

Utilization of symmetric electrode materials in energy storage application: A review

Moossa

Abraham

Kahraman

et al. 2022

Intl J of Energy Research

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“…In particular, Na 3. conductivity of the Na 3.12 Fe 2.44 (P 2 O 7 ) 2 material, which usually needs to be improved by using carbon 26 or graphene 27,28 coatings or ion doping. 29 In addition, the erosion of the material by the electrolyte during the cycling process and the resulting structural degradation problems usually result in poor cycling stability. 30,31 This is due to the dissolution of transition metals as a result of the electrolyte's side reactions on the material surface, which exacerbate the morphological and structural damage to the material and, thus, promote the penetration of the electrolyte into the particles for further reactions to take place.…”

Section: Introductionmentioning

confidence: 99%

“…In particular, Na 3.12 Fe 2.44 (P 2 O 7 ) 2 has a trilinear structure formed by centrosymmetric crowns of Fe 2 P 4 O 22 and Fe 2 P 4 O 20 molecules joined by coangular connections, with each crown unit consisting of two FeO 6 octahedra and two P 2 O 7 groups, which facilitates the reversible insertion/extraction of sodium. Nevertheless, the separation of the P 2 O 7 polyanion from the FeO 6 octahedron leads to suboptimal conductivity of the Na 3.12 Fe 2.44 (P 2 O 7 ) 2 material, which usually needs to be improved by using carbon or graphene , coatings or ion doping …”

Section: Introductionmentioning

confidence: 99%

Mg²⁺-Doping Constructed a Continuous and Homogeneous Cathode-Electrolyte Interphase Film on Na_3.12Fe_2.44(P₂O₇)₂ with Superior and Stable High-Temperature Performance for Sodium-Ion Storage

Zhang

Shao

et al. 2022

ACS Appl. Mater. Interfaces

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Sodium-ion batteries (SIBs) are on the verge of achieving practical applications, and the key is to find suitable electrode materials. The polyanionic iron-based material Na 3.12 Fe 2.44 (P 2 O 7 ) 2 (NFPO) possesses an open three-dimensional framework structure with good thermal stability and is regarded as an outstanding cathode material for SIBs. Nevertheless, its poor electrical conductivity, problems with erosion of electrolytes, and structural deterioration during cycling still need to be urgently addressed. Here, we first design a Mg 2+ -doped NFPO (NFPO-Mg) material with a dual-action effect. On the one hand, Mg 2+ improves the intrinsic conductivity of the NFPO material, and on the other hand, Mg 2+ promotes the formation of a homogeneous and stable cathode− electrolyte interphase film during the cycling process, which results in a superior rate performance and cycling stability. A capacity of 68.6 mAh g −1 was achieved at 50C (1C = 117.4 mAh g −1 ), and a capacity retention of 79.1% was maintained after 3000 cycles at 20C. More impressively, NFPO-Mg exhibits outstanding high-temperature electrochemical performance, with a capacity retention of 95.3% after 400 cycles at 10C at 60 °C (much higher than the 54.2% for the NFPO). This paper explores an effective method for improving the electrochemical performance of cathode materials, which may prove instrumental in guiding the design of more high-performance cathode materials in the future. KEYWORDS: sodium-ion battery, cathode material, Na 3.12 Fe 2.44 (P 2 O 7 ) 2 , Mg 2+ doping, cathode−electrolyte interphase

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“…Cationic substitution is usually proved to be an effective strategy to regulate structural and electrochemical properties of electrode materials. [26][27][28][29][30] In particular, it is found that manganese substitution plays critical effect on altering electrochemical properties and charge/discharge performance of Na 3 + x V 2-x Mn x -(PO 4 ) 3 , which establishes an opportunity for designing vanadium-based polyanionic cathode with improved specific energy. As demonstrated by Chen et al, [31] Mn-rich Na 4 VMn(PO 4 ) 3 composition could initially reach a high charge capacity of 156 mAh g À 1 .…”

Section: Introductionmentioning

confidence: 99%

Reversible Multi‐Electron Reaction Mechanism of Sodium Vanadium/Manganese Phosphate Cathode for Enhanced Na‐Storage Capability

et al. 2022

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Sodium-ion batteries are widely regarded as an important candidate for low cost large-scale storage of intermittent energies. NASICON-type vanadium-based phosphate with formula of Na 3 V 2 (PO 4 ) 3 exhibits promising application as cathode material for sodium-ion batteries due to robust structural framework and high electrochemical activity. However, it is intrinsically limited by low theoretical specific capacity (117 mAh g À 1 ) owing to only two-electron reaction mechanism below 4.0 V. Accordingly, exploring novel vanadium-based phosphates cathode with multi-electron reaction mechanism is essential. Herein, carbon-coated sodium vanadium/manganese phosphate (Na 3.25 V 1.75 Mn 0.25 (PO 4 ) 3 /C) was reported as enhanced cathode for sodium-ion batteries. Its structural properties, charge/discharge performance and electrochemical redox mechanism were investigated by coupling X-ray diffraction, Brunauer-Emmett-Teller measurement, X-ray photoelectron spectroscopy, cyclic voltammetry, and galvanostatic technique. It was unexpectedly found that the material not only achieved a high practical capacity (126.1 mAh g À 1 ) of larger than the theoretical value of traditional Na 3 V 2 (PO 4 ) 3 compound, but also exhibited good cycling stability with 96 % capacity retention after 40 cycles. Experimental evidences revealed that the material underwent a reversible multi-electron reaction mechanism involving V 4 + /V 3 + , Mn 3 + /Mn 2 + and V 5 + /V 4 + redox couples during Na extraction/insertion process, and the improved capacity was attributed to additional contribution of manganese substitution-activated V 5 + /V 4 + redox reaction at the high potential of ~3.8 V (vs Na + /Na).

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Chromium doping into NASICON-structured Na3V2(PO4)3 cathode for high-power Na-ion batteries

Cited by 79 publications

References 67 publications

Utilization of symmetric electrode materials in energy storage application: A review

Utilization of symmetric electrode materials in energy storage application: A review

Mg²⁺-Doping Constructed a Continuous and Homogeneous Cathode-Electrolyte Interphase Film on Na_3.12Fe_2.44(P₂O₇)₂ with Superior and Stable High-Temperature Performance for Sodium-Ion Storage

Reversible Multi‐Electron Reaction Mechanism of Sodium Vanadium/Manganese Phosphate Cathode for Enhanced Na‐Storage Capability

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Chromium doping into NASICON-structured Na3V2(PO4)3 cathode for high-power Na-ion batteries

Cited by 79 publications

References 67 publications

Utilization of symmetric electrode materials in energy storage application: A review

Utilization of symmetric electrode materials in energy storage application: A review

Mg2+-Doping Constructed a Continuous and Homogeneous Cathode-Electrolyte Interphase Film on Na3.12Fe2.44(P2O7)2 with Superior and Stable High-Temperature Performance for Sodium-Ion Storage

Reversible Multi‐Electron Reaction Mechanism of Sodium Vanadium/Manganese Phosphate Cathode for Enhanced Na‐Storage Capability

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Mg²⁺-Doping Constructed a Continuous and Homogeneous Cathode-Electrolyte Interphase Film on Na_3.12Fe_2.44(P₂O₇)₂ with Superior and Stable High-Temperature Performance for Sodium-Ion Storage