Chromium(II)-catalyzed diastereoselective pinacol type cross coupling: studies of substrate-controlled effects

Groth, Ulrich; Jung, Marc; Lang, Steffen; Schuppler, Thilo

doi:10.1016/j.tetlet.2008.10.117

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Reductive Cross‐coupling For the Formation Of 12‐difunction1

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Cited by 11 publications

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“…The intermolecular examples mostly represented dimerization reactions such as the pinacol coupling (see Equation ) . The work by Groth on chromium‐catalyzed cross‐couplings between saturated aldehydes and unsaturated aldehydes or ketones should be highlighted in this context as an exception (Equation )

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Section: Reductive Cross‐coupling For the Formation Of 12‐difunctionmentioning

confidence: 99%

Reductive Umpolung Reactions with Low-Valent Titanium Catalysts

Streuff

2014

The Chemical Record

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The coupling of similarly polarized carbon fragments can be achieved by a reductive umpolung strategy. This gives access to compounds with functional groups in even bond distances, which are difficult to synthesize by other means. Low-valent titanium catalysts enable such couplings under mild conditions. This account covers the recent progress on this topic with a focus on the development of cross-selective coupling reactions and stereoselective examples.

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Section: Reductive Cross‐coupling For the Formation Of 12‐difunctionmentioning

confidence: 99%