Humanity development is associated with higher spiritual and social behaviour and financial shape, which is an undeniable factor of urbanisation. Previously, in areas of georesource concentration, cities and settlements were formed with people exploiting these georesources. However, imperfect technologies lead to rapid depletion of reserves and industrial and environmental disasters, which affect the vulnerability of cities and the people living in them. The analysis of applied technologies has demonstrated that potash extraction is accompanied by a low recovery ratio, high mine accidents, and environmental problems. The principles of sustainable development of geo-resources for the creation of mining technologies that ensure industrial safety, environmental sustainability, and extending the life of the mining enterprise to save working places will reduce the vulnerability of cities. This article proposes the use of the room-and-pillar mining method with the replacement of natural supports with artificial ones. Three-stage stoping with backfill is considered. Numerical modelling has shown stabilisation of mining and geomechanical processes, which confirms the prospectivity of the method with backfill. For these purposes, this research presents a new backfill composition based on local industrial waste. Schemes of backfill preparation and feeding into the mined-out space are proposed. The proposed technology, based on the principles of sustainable development of georesources, is the foundation for an economically profitable, environmentally friendly, and socially responsible mining enterprise. The implementation of the principles of sustainable development of georesources will allow for the preservation of cities and reduce their vulnerability.