2024
DOI: 10.1021/acs.inorgchem.4c03675
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Circularly Polarized Phosphorescence Properties of Binuclear Cyclometalated Platinum(II) Complexes Bearing Axially Chiral Schiff-Base Ligands

Masahiro Ikeshita,
Itsuki Shimizu,
Shinya Watanabe
et al.

Abstract: The synthesis, structure, and circularly polarized phosphorescence (CPP) properties of axially chiral cyclometalated binuclear platinum(II) complexes were described. A series of optically pure binuclear platinum(II) complexes were synthesized in five steps from commercially available (R)-or (S)-1,1′-bi-2naphthol (BINOL) as starting materials. Their three-dimensional molecular structures and square-planar coordination geometries were elucidated from X-ray diffraction and 2D NMR analysis. The complexes were foun… Show more

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